The Dark Momoka Saga!

In a freak lightening accident, the violent aggressive Momoka is spun out of the usually sweet and docile one. The spiked hair Momoka using the vulgar male pronoun "ore" takes over the base and forms the new "Momoka Platoon" and starts the invasion of earth. Defeated, the inept Keroro goes into hibernation. Just as the violent Momoka is ready to push the button to launch the missile, the docile Momoka arrives in time to stop her other self from destroying Earth. They agrees to join back together in one body and will one day declare their love for Fuyuki. Keroro, revived, offers to join them through synchronized swimming. After a wonderful performance, a complete Momoka emerges from the pool. However, another complete form also emerges—the Keroro-Giroro combination.

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S01E16 - Twin At All Costs!